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Updated: Jan 29, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

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非ヘム・チオラート・リガート・コバルト・スーペロキソ・コンプレックス:合成とスペクトロスコピカルな特徴付け,計算的研究,そして水素原子抽象反応性

Jesse B Gordon1, Avery C Vilbert2, Maxime A Siegler1

  • 1Department of Chemistry , The Johns Hopkins University , 3400 North Charles Street , Baltimore , Maryland 21218 , United States.

Journal of the American Chemical Society
|February 19, 2019
PubMed
まとめ

新しいコバルト-スーパーオクソ複合体が合成され研究された. この複合体は,提案された酵素とは異なり,硫黄ドナーを酸素化する代わりに,O-H結合から水素原子を抽出し,メタロ酵素の選択性についての洞察を提供します.

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