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Updated: Jan 28, 2026

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Cp*非無罪性は,メタロセンのプロトネーションによって著しく弱いC-H結合につながります

Matthew J Chalkley1, Paul H Oyala1, Jonas C Peters1

  • 1Division of Chemistry and Chemical Engineering , California Institute of Technology (Caltech) , Pasadena , California 91125 , United States.

Journal of the American Chemical Society
|February 22, 2019
PubMed
まとめ

コバルトセンの誘導体のプロトネーションにより,リングプロトネーションされたイソマー,Cp*(exo/endo-η4-C5Me5H) Co+が検出される. この研究は,これらの種とその非常に弱いC−H結合の特徴を明らかにし,これは還元性触媒の理解に不可欠である.

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