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分子内水素結合相互作用によって促進されるヘム-ペロキソ-銅複合体のスピン相互変換

Andrew W Schaefer1, Melanie A Ehudin2, David A Quist2

  • 1Department of Chemistry , Stanford University , Stanford , California 94305 , United States.

Journal of the American Chemical Society
|March 6, 2019
PubMed
まとめ

水素結合能力を持つ合成ペロキソブリッジ銅ヘム複合体は,可逆スピンクロスオーバー (SCO) を表している. 分子内H結合は低スピン状態を安定させ,電子構造に影響を与え,温度依存のスピン状態の相互変換を可能にします.

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