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Updated: May 3, 2026

High-throughput Synthesis of Carbohydrates and Functionalization of Polyanhydride Nanoparticles
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High-throughput Synthesis of Carbohydrates and Functionalization of Polyanhydride Nanoparticles

Published on: July 6, 2012

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3,5-ジメチル-4-(2'-フェニルチニル) フェニル (EPP) グリコシドによるデオロマティブ活性化メカニズムによるグリコシレーション

Zhifei Hu1, Yu Tang2, Biao Yu2

  • 1School of Physical Science and Technology , ShanghaiTech University , 100 Haike Road , Shanghai 201210 , China.

Journal of the American Chemical Society
|March 14, 2019
PubMed
まとめ

効率的な合成のために3,5-ジメチル-4-(2'-フェニルチニル) フェニル (EPP) グリコシドを使用する新しいグリコシレーション法. このアプローチは,炭水化物の化学における多用途性を提供するユニークなオロマティブアクティベーションメカニズムを通じます.

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Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.
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Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of peroxy...
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