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Monitoring Conformational Dynamics of Single Unmodified Proteins using Plasmonic Nanotweezers
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ディフェナントリオクタフィリン ((1.1.0.1.1.1.0):コンフォームショナルのスイッチングは,トポロジカルキラルシステムのステレオ化学的ダイナミクスを制御する

Bartosz Szyszko1, Piotr J Chmielewski1, Monika Przewoźnik1

  • 1Department of Chemistry , University of Wrocław , 14 F. Joliot-Curie Street , 50-383 Wrocław , Poland.

Journal of the American Chemical Society
|March 22, 2019
PubMed
まとめ

ディメトキシフェナントレン単位で合成されたオクタフィリン類は,2つの分離可能なコンフォマーとして存在します. ボロン複合は選択的に1つの形状を安定させ,すべてのシステムは異なるステレオダイナミックな行動とエナティオメア分離を示します.

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