Ran Lu1, Liya Cao1, Honghao Guan2

  • 1School of Pharmaceutical Sciences , Shandong University , Jinan 250012 , China.

まとめ

新しい鉄触媒法により,循環性二次アミンの効率的な動的解像度が空気を用いて達成される. この実用的なアプローチは,複雑な生物活性分子中間物質を含む,エナチオメリックに濃縮されたアミンを生成します.

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Nomenclature of Secondary and Tertiary Amines01:12

Nomenclature of Secondary and Tertiary Amines

The secondary and tertiary amines are derivatives of ammonia, where two and three of its hydrogens are replaced by alkyl groups, respectively. Secondary and tertiary amines can be symmetrical with identical alkyl groups attached to the nitrogen atom or unsymmetrical when more than one type of alkyl group is present. The standard nomenclature of secondary and tertiary amines is similar to the names given to the primary amines. They are generally named alkylamines. As depicted in Figure 1, for...
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Preparation of Amines: Alkylation of Ammonia and Amines01:30

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Alkylation is one of the methods used to prepare amines. Direct alkylation of ammonia or a primary amine with an alkyl halide gives polyalkylated amines along with a quaternary ammonium salt through successive SN2 reactions. This process of making the quaternary salt through the direct alkylation method is called exhaustive alkylation.
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