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Updated: Jan 26, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
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白からサイクロテトラフォスファンの直接機能化:P-C結合の選択的形成

Shanshan Du1, Jimin Yang2, Jingyuan Hu1

  • 1Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry , Peking University , Beijing 100871 , China.

Journal of the American Chemical Society
|April 18, 2019
PubMed
まとめ

研究者らはアルミナcyclopentadienes を使用して白をオルガノフォスファース化合物に変換しました. この反応は,新しいカスケードプロセスを通してサイクロテトラフォスファンを形成し,フォスフォリルアニオンとカチオンへのさらなる機能化を可能にします.

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