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Updated: Apr 7, 2026

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
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Fe-Biphenyl-4,4'-dicarboxylate金属有機フレームワークにおける相互浸透の運動制御

Dominic Bara1, Claire Wilson1, Max Mörtel2

  • 1WestCHEM School of Chemistry , University of Glasgow , Joseph Black Building, University Avenue , Glasgow G12 8QQ , U.K.

Journal of the American Chemical Society
|April 25, 2019
PubMed
まとめ

研究者は,調整と酸化調節を使用して,金属有機フレームワーク (MOF) の自己組み立てを制御します. この方法は,高表面積で純正なMIL-126 (Fe) を達成するために,動力学的および熱力学的製品の間で信頼性の高いチューニングを行います.

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
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Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
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