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Updated: Jan 25, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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カタリティック・ラジカル・アルケンのクロスカップリングにおける鉄複合体の役割:計算とメカニズムの研究

Dongyoung Kim1, S M Wahidur Rahaman2, Brandon Q Mercado1

  • 1Department of Chemistry , Yale University , New Haven , Connecticut 06511 , United States.

Journal of the American Chemical Society
|April 27, 2019
PubMed
まとめ

鉄触媒によるアルケンのクロスカップリング反応は,水素原子移転 (HAT) を利用して基質を形成する. この研究は,速度を制限するステップと,効率的なカップリングのために不可逆的なHATを駆動する弱い鉄水化結合の重要な役割を明らかにします.

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