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活性化マグネシウム (I) 化合物を用いて,COをデルタートダイアニオンに還元性トリメリゼーション

K Yuvaraj1, Iskander Douair2, Albert Paparo1

  • 1School of Chemistry , Monash University , P.O. Box 23, Melbourne , VIC 3800 , Australia.

Journal of the American Chemical Society
|May 18, 2019
PubMed
まとめ

延長されたMg-Mg結合を持つ新しいマグネシウム (I) コンプレックスが合成された. これらの複合体は,炭素一酸化物 (CO) を還元的にトリメリ化して希少なデルタートダイアニオン構造を形成し,C−C結合形成の洞察を提供します.

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