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Updated: Jan 24, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

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エンジニアリングカルベントランスファーゼによって可能になったステレオダイバーゲント内分子サイクロプロパネーション

Ajay L Chandgude1, Xinkun Ren1, Rudi Fasan1

  • 1Department of Chemistry , University of Rochester , 120 Trustee Road , Rochester , New York 14627 , United States.

Journal of the American Chemical Society
|May 18, 2019
PubMed
まとめ

エンジニアリングされたミオグロビン生物触媒は,無対称な分子内サイクロプロパネーションを行い,価値あるサイクロプロパンと融合したγ-ラクトンを生成します. この新しい生物触媒的アプローチは,医薬品化学と天然製品の合成のためのステレオダイバージェント合成を可能にします.

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