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Metallic Solids02:37

Metallic Solids

20.5K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.5K
Bonding in Metals02:32

Bonding in Metals

52.1K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
52.1K
Alkali Metals03:06

Alkali Metals

24.2K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
24.2K
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

24.1K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.1K
Properties of Transition Metals02:58

Properties of Transition Metals

29.7K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
29.7K
Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

5.8K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
5.8K

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Updated: Jan 22, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
10:57

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

19.0K

原子的に薄い金属硫化物

Lenore Kubie1, Marissa S Martinez1,2, Elisa M Miller1

  • 1Chemistry and Nanoscience Center , National Renewable Energy Laboratory , Golden , Colorado 80401 , United States.

Journal of the American Chemical Society
|July 6, 2019
PubMed
まとめ
この要約は機械生成です。

研究者は,原子的に薄い金属硫化物 (ATMS) を合成するための新しい方法を開発しました. これらの新しい2D素材は,従来の形とは異なる独特の光学特性を有しています.

さらに関連する動画

Separation of Uranium and Thorium for 230Th-U Dating of Submarine Hydrothermal Sulfides
08:43

Separation of Uranium and Thorium for 230Th-U Dating of Submarine Hydrothermal Sulfides

Published on: May 20, 2019

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Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
08:40

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

4.2K

関連する実験動画

Last Updated: Jan 22, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
10:57

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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Separation of Uranium and Thorium for 230Th-U Dating of Submarine Hydrothermal Sulfides
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Separation of Uranium and Thorium for 230Th-U Dating of Submarine Hydrothermal Sulfides

Published on: May 20, 2019

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Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
08:40

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

4.2K

科学分野:

  • 材料科学
  • ナノテクノロジー
  • 固体化学

背景:

  • 原子的に薄い材料は MoS2やグラフェンのような 層状の構造です
  • 非層の散発材料は,2D形式の生産のための確立された方法がない.

研究 の 目的:

  • 非層の原子薄金属硫化物 (ATMS) のコロイド合成方法を開発する.
  • この新しい二次元材料の性質を 探求するためです

主な方法:

  • カチオン交換反応によるコロイド合成.
  • シルバー硫化物 (Ag2S) を前体として利用する.
  • Z型およびL型リガンドを用いた合成ATMSの安定化.

主要な成果:

  • 単層と少層のZnS,CdS,CoS2,PbSをカオン交換で成功して合成した.
  • 合成されたATMSは5〜10nmの横の寸法で,サイズと形を維持します.
  • 血小板または量子ドット形式と比較して合成されたATMSの独特の光学特性を観察した.

結論:

  • カチオン交換法により,非層のATMSの生成が可能である.
  • これらの新しい2D材料は,潜在的なアプリケーションにユニークな光学特性を提供します.
  • 合成アプローチは,従来の層状の化合物を超えて,アクセシブルな2D素材のライブラリを拡張します.