高度に秩序付けられた共価シエルピンスキー三角形の表面合成
Yiping Mo1,2, Ting Chen1, Jingxin Dai3
1CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190 , China.
Journal of the American Chemical Society
|July 11, 2019
まとめ
研究者は単純な脱水反応を用いて,安定した分子サイルピンスキー三角形 (STs) を作成した. これらの共性フラクタルは,グラファイト表面との相互作用により,第3世代まで独特のコントラストを示します.
科学分野:
- 材料科学
- 超分子化学
- 表面科学
背景:
- シェルピンスキー三角 (ST) のようなフラクタル構造は,非常に興味深いものです.
- 強い共性結合を持つ 安定した分子フラクタルを作ることは 合成的な課題です
研究 の 目的:
- 高品質の共価シエルピンスキー三角形の形成を証明する.
- 表面上の反応を用いて 分子フラクタルの合成を研究する.
主な方法:
- 1,3-ベンゼンジボロン酸の表面脱水反応
- 環境条件下で水をバランスレギュラーとして利用する.
- スキャントンネル顕微鏡 (STM) と理論的シミュレーションを用いた特徴付け.
主要な成果:
- 第3世代まで拡張された共角シエルピンスキー三角形の形成.
- 明らかに明るいと暗いコントラストの観察
- フラクタル構造とシミュレーションによる基礎グラフィット格子との相関.
結論:
- 安定した共性分子サーピンスキー三角形の成功合成は可能である.
- 観測されたコントラストは,フラクタルとグラファイト基板の間の表層関係に起因する.
関連する概念動画
Covalent Bonds
160.5K
Overview
160.5K
Covalent Bonds
10.1K
Overview
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
10.1K
Network Covalent Solids
16.1K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.1K
Covalently Linked Protein Regulators
8.8K
Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
These groups modify specific amino acids in a protein....
These groups modify specific amino acids in a protein....
8.8K
Covalently Linked Protein Regulators
2.0K
2.0K
Covalent Bonding and Lewis Structures
60.8K
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
60.8K


