Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Metallic Solids02:37

Metallic Solids

20.5K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.5K
Thermal Expansion01:22

Thermal Expansion

5.6K
The expansion of alcohol in a thermometer is one of many commonly encountered examples of thermal expansion, which is the change in size or volume of a given system as its temperature changes. The most visible example is the expansion of hot air. When air is heated, it expands and becomes less dense than the surrounding air, which then exerts an upward force on the hot air to, for example, make steam and smoke rise, and hot air balloons float. The same behavior happens in all liquids and gases,...
5.6K
Thermal expansion and Thermal stress: Problem Solving01:27

Thermal expansion and Thermal stress: Problem Solving

2.1K
San Francisco's Golden Gate Bridge is exposed to temperatures ranging from -15 °C to 40 °C. At its coldest, the main span of the bridge is 1275 m long. Assuming that the bridge is made entirely of steel, what is the change in its length between these temperatures?
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in temperature (ΔT) is 55...
2.1K
Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

2.6K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
2.6K
Bonding in Metals02:32

Bonding in Metals

52.1K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
52.1K
Alkali Metals03:06

Alkali Metals

24.2K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
24.2K

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Xenon/Krypton Separation on a Bromine Functionalized Benzimidazole-Linked Porous Covalent Organic Polymer.

ACS applied materials & interfaces·2026
Same author

Cationic Covalent Organic Framework-Based Membranes for High-Performance Zn/Br<sub>2</sub> Redox Flow Batteries.

Small (Weinheim an der Bergstrasse, Germany)·2025
Same author

Xenon adsorption-induced flexibility of the zeolitic imidazolate framework ZIF-4 observed by <i>in situ</i><sup>129</sup>Xe NMR spectroscopy.

Chemical communications (Cambridge, England)·2025
Same author

Orientational Disorder of NH<sub>3</sub> in Hexammine Magnesium Borohydride.

Inorganic chemistry·2025
Same author

Carboranes without Cage Carbons: <i>closo</i>-Dodecaborate Mimics of Neutral <i>closo</i>-Carboranes.

Journal of the American Chemical Society·2025
Same author

The role of surface deformation on responsivity of the pillared layer metal-organic framework DUT-8(Ni).

Chemical science·2025

関連する実験動画

Updated: Jan 22, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
07:14

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

3.8K

メタル・オーガニック・フレームワークにおける熱膨張の調整

Samuel J Baxter1, Andreas Schneemann1, Austin D Ready1

  • 1Sandia National Laboratory , Livermore , California 94550 , United States.

Journal of the American Chemical Society
|July 20, 2019
PubMed
まとめ

研究者は,金属有機フレームワーク (MOF) の負から正の熱膨張の継続的な調節を実現し,固体溶液を作成しました. この突破はMOFの熱特性に対する新しい制御を提供します.

科学分野:

  • 材料科学
  • 化学について
  • 固体物理学

背景:

  • メタル・オーガニック・フレームワーク (MOF) は,負の熱膨張 (NTE) を示すことが知られている.
  • 一つのMOFフェーズで熱膨張をネガティブからポジティブに継続的に調整することはこれまで報告されていません.
  • 伝統的なNTE材料にはこの調節可能な特性がない.

研究 の 目的:

  • MOFシステムにおける熱膨張の継続的なチューニングを調査する.
  • 熱膨張を制御するための単相固体溶液の形成を調査する.
  • MOFにおける熱膨張の調整のための一般的な戦略を確立する.

主な方法:

  • Zn-DMOF-TMシステムで一連の混合リンカー固体溶液の合成.
  • 合成されたMOFの熱膨張特性の特徴.
  • 熱膨張行動に影響を与える構造変化の分析.

主要な成果:

  • ネガティブからプラスの熱膨張へのスムーズな移行は,四角形の材料のa-b平面で観察されました.
  • 熱膨張ゼロの温度は,TM-bdc含有量が増加するにつれて~186Kから~325Kに変化した.
  • 単相固体溶液の成功形成により,継続的な熱膨張チューニングが可能になった.

さらに関連する動画

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.1K
A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
10:13

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

Published on: April 28, 2023

3.0K

関連する実験動画

Last Updated: Jan 22, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
07:14

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

3.8K
Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.1K
A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
10:13

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

Published on: April 28, 2023

3.0K

結論:

  • 混合リンク器の固体溶液は,MOFの熱膨張を制御するための実行可能で一般的な戦略です.
  • この研究は,単一のMOFシステムにおける熱膨張の前例のない調整性を示しています.
  • この発見は,特定の熱膨張特性を持つMOFの設計のための道を開く.