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Atomic Mass01:52

Atomic Mass

69.7K
Atoms — and the protons, neutrons, and electrons that compose them — are extremely small. For example, a carbon atom weighs less than 2 × 10−23 g. When describing the properties of tiny objects such as atoms, we use appropriately small units of measure, such as the atomic mass unit (amu). The amu was originally defined based on hydrogen, the lightest element, then later in terms of oxygen. Since 1961, it has been defined with regard to the most abundant isotope of carbon, atoms of which...
69.7K
Network Covalent Solids02:18

Network Covalent Solids

16.1K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.1K
Atomic Number and Mass Number01:12

Atomic Number and Mass Number

14.8K
The number of protons in the nucleus of an atom is its atomic number (Z). This is the defining trait of an element. Its value determines the identity of the atom. For example, any atom that contains six protons is the element carbon and has the atomic number 6, regardless of how many neutrons or electrons it may have. A neutral atom must contain the same number of positive and negative charges, so the number of protons equals the number of electrons. This means that the atomic number also...
14.8K
Hybridization of Atomic Orbitals I03:24

Hybridization of Atomic Orbitals I

66.0K
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
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Atomic Structure01:33

Atomic Structure

207.3K
Overview
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General Properties of Solutions02:12

General Properties of Solutions

35.5K
Many common substances around us exist as a solution, such as ocean water, air, and gasoline. All solutions are mixtures of substances that are composed of varying amounts of two or more types of atoms or molecules. A mixture with a non-uniform composition is a heterogeneous mixture, whereas a mixture with a uniform composition is a homogeneous mixture. The components that make the homogeneous mixture are evenly spread out and thoroughly mixed. 
35.5K

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関連する実験動画

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Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
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Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

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六角ボロンネットワークによる2D原子層の溶液相質量合成

Tetsuya Kambe1,2, Reina Hosono1, Shotaro Imaoka1

  • 1Laboratory for Chemistry and Life Science, Tokyo Institute of Technology , Yokohama 226-8503 , Japan.

Journal of the American Chemical Society
|August 3, 2019
PubMed
まとめ

研究者は,ボロフェンのアナログである平面性原子ボロンネットワークを,カリウムボロヒドリドを用いて合成した. この新しい2D素材は 金属の伝導性を示し,先進的な電子アプリケーションの道を開きます.

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Author Spotlight: Integrating 2D-HPLC-MS and Molecular Networking in Natural Medicine Analysis
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Absolute Quantification of Cell-Free Protein Synthesis Metabolism by Reversed-Phase Liquid Chromatography-Mass Spectrometry
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Absolute Quantification of Cell-Free Protein Synthesis Metabolism by Reversed-Phase Liquid Chromatography-Mass Spectrometry
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科学分野:

  • 材料科学
  • 固体物理学
  • ナノテクノロジー

背景:

  • ボロフェンとその類型はユニークな性質を持つ2D材料です.
  • これらの材料のための新しい合成方法を探求することは極めて重要です.

研究 の 目的:

  • 平面的な原子ボロンネットワークの ダウンアップ合成を実現する.
  • このボロフェンの類型を 安定化して特徴づけるために
  • 電子特性を調べるため

主な方法:

  • ボトムアップ合成で,ボロヒドリドカリウム (KBH4) を使用する.
  • 酸素原子を用いたボロンネットワークの安定化.
  • 結晶の積み重ねはカリウムカチオンによって促進される.
  • 電子特性分析のための導電性測定

主要な成果:

  • 平面的な原子ボロンネットワーク (ボロフェンアナログ) の成功合成.
  • 平面内の酸素原子によって安定化され,穴とアニオン状態が生まれます.
  • カリウムのカチオンは 層の積み重ねと 原子的に薄い層に溶解を可能にしました
  • 平面内伝導性の測定は,ほぼゼロの活性化エネルギーで金属の振る舞いを示した.

結論:

  • 合成された物質は,新しい平面ボロフェンアナログを表しています.
  • この材料は,平面内での金属伝導性が顕著である.
  • この発見は新しい 2D 電子材料への道を開きます