ポリモルフなナノドメイン設計による超高エネルギー密度の無鉛介電膜
1State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, China.
まとめ
研究者はポリモルフなナノドメインを用いて超高エネルギー密度の新型介電材料を開発した. エネルギー貯蔵におけるこの画期的な進歩は 電気と電子システムの 重要な改善をもたらします
科学分野:
- 材料科学
- 固体物理学
- エネルギー貯蔵
背景:
- エネルギー貯蔵には不可欠ですが エネルギー密度の向上は課題です
- 現在の介電材料は,高いエネルギー密度と効率の両方を達成する上でしばしば制限に直面します.
研究 の 目的:
- 超高エネルギー密度の無鉛介電材料を設計し合成する.
- ポリモルフなナノドメインが介電性能を改善する役割を調査する.
主な方法:
- 材料設計を導くために相場シミュレーションを使用した.
- 合成されたBiFeO3-BaTiO3-SrTiO3固溶液フィルム
- ナノドメインの構造と介電特性を特徴づけた.
主要な成果:
- 超高エネルギー密度112J/cm3を達成した.
- 約80%の高いエネルギー効率が得られました.
- 高極化を維持しながらヒステリシスを最小限に抑える
結論:
- 多形ナノドメインは高性能介電剤の設計に有効である.
- 開発された無鉛材料は,先進的なエネルギー貯蔵のための有望な解決策を提供します.
- このアプローチは,ナノスケールドメイン構造を持つ他の機能的材料に一般化できます.
関連する概念動画
Strain-Energy Density
854
Understanding the strain energy density in materials under axial load is crucial for evaluating their mechanical behavior and durability. When a rod is subjected to such a load, it elongates and stores energy, known as strain energy, as potential energy within the material. This energy is measured in terms of energy per unit volume.
In the elastic region of a material, the relationship between the stress and the strain is linear and follows Hooke's Law. The strain energy density in this region...
In the elastic region of a material, the relationship between the stress and the strain is linear and follows Hooke's Law. The strain energy density in this region...
854
Capacitor With A Dielectric
4.8K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
4.8K
Gauss's Law in Dielectrics
5.1K
Consider a polar dielectric placed in an external field. In such a dielectric, opposite charges on adjacent dipoles neutralize each other, such that the net charge within the dielectric is zero. When a polar dielectric is inserted in between the capacitor plates, an electric field is generated due to the presence of net charges near the edge of the dielectric and the metal plates interface. Since the external electrical field merely aligns the dipoles, the dielectric as a whole is neutral. An...
5.1K
Ionization Energy
43.0K
The amount of energy required to remove the most loosely bound electron from a gaseous atom in its ground state is called its first ionization energy (IE1). The first ionization energy for an element, X, is the energy required to form a cation with 1+ charge:
43.0K
Gibbs Free Energy
38.0K
One of the challenges of using the second law of thermodynamics to determine if a process is spontaneous is that it requires measurements of the entropy change for the system and the entropy change for the surroundings. An alternative approach involving a new thermodynamic property defined in terms of system properties only was introduced in the late nineteenth century by American mathematician Josiah Willard Gibbs. This new property is called the Gibbs free energy (G) (or simply the free...
38.0K
What is Energy?
58.4K
The universe is composed of matter in different forms, and all forms of matter contain energy. The different forms of energy on Earth originate from the Sun — the ultimate energy source. Plants capture light energy from the Sun, and, via the process of photosynthesis, convert it into chemical energy. This stored energy from plants can be harnessed in many ways. For example, eating plant products as food provides energy for our body to function, and burning wood or coal (fossilized...
58.4K


