Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Competition02:34

Competition

24.3K
When organisms require the same limited resources within an environment, they may have to compete for them. Competition is a net-negative interaction. Even if two competing individuals or populations do not interact directly, the overall fitness of both competitors is lowered as a result of not having full access to the limited resource.
24.3K
The Nitrogen Cycle01:49

The Nitrogen Cycle

59.6K
Nitrogen atoms, present in all proteins and DNA, are recycled between abiotic and biotic components of the ecosystem. However, the primary form of nitrogen on Earth is nitrogen gas, which cannot be used by most animals and plants. Thus, nitrogen gas must first be converted into a usable form by nitrogen-fixing bacteria before it can be cycled through other living organisms. The use of nitrogen-containing fertilizers and animal waste products in human agriculture has greatly influenced the...
59.6K
Overview of Nitrogen Metabolism01:20

Overview of Nitrogen Metabolism

11.0K
Nitrogen is a very important element for life because it is a major constituent of proteins and nucleic acids. It is a macronutrient, and in nature, it is recycled from organic compounds and stored in the form of  ammonia, ammonium ions, nitrate, nitrite, or  nitrogen gas by many metabolic processes. Many of these metabolic processes are carried out only by prokaryotes.
The largest pool of nitrogen available in the terrestrial ecosystem is gaseous nitrogen (N2) from the air, but this...
11.0K
The Carbon Cycle01:14

The Carbon Cycle

43.3K
Carbon is the basis of all organic matter on Earth, and is recycled through the ecosystem in two primary processes: one in which carbon is exchanged among living organisms, and one in which carbon is cycled over long periods of time through fossilized organic remains, weathering of rocks, and volcanic activity. Human activities, including increased agricultural practices and the burning of fossil fuels, has greatly affected the balance of the natural carbon cycle.
43.3K
Carbon Skeletons01:12

Carbon Skeletons

114.2K
Life on Earth is carbon-based, as all macromolecules that make up living organisms contain carbon atoms. All organic compounds have a carbon backbone. Each carbon atom is tetravalent and can bond with four other atoms, making it an extraordinarily flexible component of biological molecules. Because carbon’s valence electrons are stable, it rarely becomes an ion. As the carbon chain increases in length, structural modifications such as ring structures, double bonds, and branching side...
114.2K
Inorganic Nitrogen Assimilation01:22

Inorganic Nitrogen Assimilation

489
Nitrogen is an essential element in biological systems, forming a crucial component of proteins, nucleic acids, and other cellular constituents. Many bacteria and archaea acquire nitrogen in the form of nitrate (NO₃⁻) or ammonia (NH₃), which are then assimilated into biomolecules through specific enzymatic pathways.Assimilatory Nitrate ReductionWhen nitrate enters the cell, it undergoes a two-step reduction process known as assimilatory nitrate reduction. Initially, the enzyme...
489

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

First Evidence for Ozonido-TMC Complexes of Iron and Cobalt.

Angewandte Chemie (International ed. in English)·2026
Same author

The Sulfur Monoxide-Water Complex.

Journal of the American Chemical Society·2026
Same author

Bottom-Up Formation of the Simplest Geminal Thiol─Methanedithiol (CH<sub>2</sub>(SH)<sub>2</sub>)─and the Methyl Hydrodisulfide (H<sub>3</sub>CSSH) Isomer in Interstellar Analogue Ices.

The journal of physical chemistry letters·2026
Same author

Isoniazid-Saccharin Salts: Synthesis, Structural Aspects, Thermal Properties and Spectroscopic Characterization.

Molecules (Basel, Switzerland)·2026
Same author

Laser-Induced and Spontaneous Conformational Transformations in Monomers of Isoguanine Isolated in Low-Temperature Ar and Ne Matrices.

Precision chemistry·2026
Same author

Assessing Benzene Dimer Interactions in Solution With a Molecular Balance.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026

関連する実験動画

Updated: Jan 20, 2026

Biofilm Removal Using Carbon Dioxide Aerosols without Nitrogen Purge
07:11

Biofilm Removal Using Carbon Dioxide Aerosols without Nitrogen Purge

Published on: November 6, 2016

6.8K

競争力のある窒素と炭素のトンネル

Cláudio M Nunes1, André K Eckhardt2, Igor Reva1

  • 1CQC, Department of Chemistry , University of Coimbra , 3004-535 Coimbra , Portugal.

Journal of the American Chemical Society
|August 20, 2019
PubMed
まとめ

炭素と窒素の重原子量子力学トンネリング (QMT) は,これまで考えられていたよりも一般的です. この研究は,これらのQMT経路が競合し,同じ分子から異なる製品を生成することを示しています.

科学分野:

  • 物理化学
  • 量子化学について
  • 化学的動力学

背景:

  • 重原子量子力学トンネリング (QMT) は歴史的に不可能と考えられていた.
  • 最近の発見は,重原子QMTが予想以上に頻繁に発生することを示しています.

研究 の 目的:

  • 炭素対窒素重原子QMTの競争性を調査する.
  • 異なる製品が競合するQMT経路で同じ原料から生じる可能性があることを実証する.

主な方法:

  • アミノ置換ベンザジリンを固体アルゴンで冷凍温度 (3~18K) で生成する.
  • 暗闇で自発的な分解を監視し,反応半減期を決定する.
  • 量子化学計算を使って 反応経路を分析する

主要な成果:

  • アミノ置換されたベンザジリンの自発的な分解が観察され,半減期は210分であった.
  • 2つの異なる製品:p-アミノフェニルニトレンとアミノ置換ケテニミンを特定した.
  • 反応速度は温度に依存しないことが判明し,古典的な移行状態理論に反する.
  • 量子化学計算では 炭素対窒素の2つの競合する QMT 経路が確認されました

さらに関連する動画

Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers
11:58

Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers

Published on: May 13, 2013

23.4K
Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
10:44

Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis

Published on: February 12, 2019

10.4K

関連する実験動画

Last Updated: Jan 20, 2026

Biofilm Removal Using Carbon Dioxide Aerosols without Nitrogen Purge
07:11

Biofilm Removal Using Carbon Dioxide Aerosols without Nitrogen Purge

Published on: November 6, 2016

6.8K
Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers
11:58

Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers

Published on: May 13, 2013

23.4K
Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
10:44

Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis

Published on: February 12, 2019

10.4K

結論:

  • 炭素と窒素の重原子のQMTは競争力があり,単一の前体から複数の製品が生成されます.
  • 温度に依存しない反応速度は 量子力学的効果を古典的な予測よりも強調しています
  • この研究は,化学反応と分子行動における量子現象の重要な役割を強調しています.