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Updated: Jan 19, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
12:19

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

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N-ヘテロサイクリックカルベンで保護された頑丈で高発光するAu13超原子

Mina R Narouz1, Shinjiro Takano2, Paul A Lummis1

  • 1Department of Chemistry , Queen's University , Chernoff Hall, Kingston , Ontario K7L 3N6 , Canada.

Journal of the American Chemical Society
|September 10, 2019
PubMed
まとめ

新しい金超原子ナノクラスターは,N-ヘテロサイクリックカルベン (NHCs) によって安定化され,光発光が強化されています. これらのNHC-Auクラスターは高い安定性と大きなエネルギーギャップを示し,以前のリガンドで保護された金ナノクラスターを上回ります.

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Detailed and generalized protocols are presented for the synthesis and subsequent purification of four palladium N-heterocyclic carbene complexes from benzimidazolium salts. The complexes were tested for catalytic activity in arylation and Suzuki-Miyaura reactions. For each reaction investigated, at least one of the four complexes successfully catalyzed the...
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