"スピンコーティング エピタキシアルフィルム"に関するコメント
1College of Physics, State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, Shandong 266071, China. cjlu@qdu.edu.cn.
まとめ
この研究は,スピンコーティングによって作られたエピタキシアル無機膜の主張に異議を唱える. ポールフィギュアの分析は,膜が本当に表表表軸性でないことを示唆する,表表軸性粒子の低い割合を示しています.
科学分野:
- 材料科学
- クリスタルグラフィー
背景:
- スピンコーティングは薄膜を積む方法である.
- エピタキシアル成長には,フィルムと基板の間の特定の結晶学的な方向性が必要です.
研究 の 目的:
- スピンコーティングによって生成されたエピタキシアル無機膜の主張を再評価する.
- ケルソ等によって蓄積されたフィルムにおけるエピタキシの実際の程度を決定する.
主な方法:
- 結晶学的構造を分析するためにX線微分法 (XRD) が使用された.
- ポールフィギュア分析は,フィルム内の粒子の方向性を定量化するために使用されました.
主要な成果:
- フィルムは4. 1から25. 5パーセントの表面粒だけを含んでいた.
- エピタキシアル粒子の計算された割合は,真のエピタキシアル成長の欠如を示しています.
結論:
- Kelso et al. が報告したように,スピンコーティングによって堆積した無機膜は,エピタキシアルとは考えられない.
- これらの発見は,これらの材料で高品質の表軸成長を達成するためのスピンコーティングの限界を示唆しています.
関連する概念動画
SN1 Reaction: Stereochemistry
8.7K
This lesson provides an in-depth discussion of the stereochemical outcomes in an SN1 reaction.
In the first step of an SN1 reaction, the bond between the electrophilic carbon and the leaving group ionizes to generate the carbocation intermediate. The second step of the mechanism is the nucleophilic attack.
In the formed carbocation, the positively charged carbon is sp2 hybridized with a trigonal planar geometry. As all the three substituents lie on the same plane, a plane of symmetry for the...
In the first step of an SN1 reaction, the bond between the electrophilic carbon and the leaving group ionizes to generate the carbocation intermediate. The second step of the mechanism is the nucleophilic attack.
In the formed carbocation, the positively charged carbon is sp2 hybridized with a trigonal planar geometry. As all the three substituents lie on the same plane, a plane of symmetry for the...
8.7K
Polymer Classification: Stereospecificity
2.3K
Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
2.3K
Olefin Metathesis Polymerization: Overview
1.8K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
1.8K
Effects of EDTA on End-Point Detection Methods
819
Different methods, such as visual observance of metal-ion indicators, spectroscopic techniques, and potentiometric methods, can determine the endpoint of an EDTA titration.
In the visual method, metal-ion indicators (metallochromic dyes), which have distinct colors in their free and complex forms, are added to the mixture to signal the titration's end point. They form stable complexes with metal ions, but these complexes are weaker than the corresponding metal–EDTA complexes. As a...
In the visual method, metal-ion indicators (metallochromic dyes), which have distinct colors in their free and complex forms, are added to the mixture to signal the titration's end point. They form stable complexes with metal ions, but these complexes are weaker than the corresponding metal–EDTA complexes. As a...
819
Antiplatelet Drugs: Prostaglandin Synthesis, P2Y12 and Glycoprotein IIb/IIIa Inhibitors
1.6K
Antiplatelet drugs emerge as frontline defenders against the insidious threat of thromboembolic diseases, where abnormal clots obstruct vital blood vessels. These drugs stand as bulwarks, inhibiting platelet aggregation and clot formation, thereby mitigating the risk of life-threatening conditions like myocardial infarction, coronary artery disease, and thrombotic strokes.
Prostaglandin synthesis inhibitors, exemplified by the widely known aspirin, wield their power by irreversibly acetylating...
Prostaglandin synthesis inhibitors, exemplified by the widely known aspirin, wield their power by irreversibly acetylating...
1.6K
Production of Pharmaceuticals
94
Industrial insulin production uses genetically engineered E. coli expressing a proinsulin gene controlled by a tryptophan promoter and containing a methionine linker for later cleavage. The cells also carry ampicillin resistance for selective growth. Seed cultures are stored at −80 °C and production begins by thawing a small amount to inoculate starter cultures, which are progressively scaled to a 50,000-L bioreactor. In the bioreactor, E. coli grow in nutrient-rich media under...
94


