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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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可視光誘導による,金属のないカルベンの挿入は,アシルシランとピナコルボラン間のB-H結合に

Jian-Heng Ye1, Linda Quach1, Tiffany Paulisch1

  • 1Organisch-Chemisches Institut , Westfälische Wilhelms-Universität Münster , Corrensstraße 40 , 48149 Münster , Germany.

Journal of the American Chemical Society
|September 28, 2019
PubMed
まとめ

可視光は,アシルシランを用いてB-H結合に無金属カルベンの挿入を可能にします. この効率的な反応は,穏やかな条件下で様々なα-アルコキシオルガノボロナートエステルを合成する.

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