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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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内部分子ビルスマイヤー型反応による反芳香膨張アザコロネの合成と分離

Kosuke Oki1, Masayoshi Takase1, Shigeki Mori2

  • 1Graduate School of Science and Engineering , Ehime University , Matsuyama 790-8577 , Japan.

Journal of the American Chemical Society
|October 3, 2019
PubMed
まとめ

研究者らは,拡張ヘキサピロヘキサカロネン (HPHAC) の抗芳香カチオンを合成した. この新しい化合物は,NMRスペクトロスコーピーと計算研究によって確認された24πの反芳香性を示し,芳香的トリケーションに変換することができます.

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