nπ*

Erik C Vik1, Ping Li1, Perry J Pellechia1

  • 1Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States.

まとめ

分子ロータは,n→π*相互作用が,結合回転の移行状態 (TS) を著しく安定させることを実証している. 10 kcal/molまでのこの安定化は,計算研究とNBO分析によって確認された.

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