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Updated: Jan 4, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

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狭い幾何学におけるオレフィンメタテシス:選択的なマクロサイクリングに向けたバイオミメティックアプローチ

Felix Ziegler, Johannes Teske, Iris Elser

  • 1Institute of Thermodynamics and Thermal Process Engineering , University of Stuttgart , Pfaffenwaldring 9 , D-70569 Stuttgart , Germany.

Journal of the American Chemical Society
|November 8, 2019
PubMed
まとめ

この研究は,環閉メタテシスにおけるマクロサイクリングの選択性を高めるために,オーダーされたメソポラスシリカ内の空間的閉じ込みを用いたバイオミメティックアプローチを導入している. この方法は,オリゴマーの形成を大幅に減らし,望ましいマクロサイクル製品の収量を改善します.

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