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Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
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前シサナタニンCの非対称的全合成

Yan-Long Jiang1, Hai-Xin Yu1, Yong Li1

  • 1Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education and Beijing National Laboratory for Molecular Science (BNLMS), and Peking-Tsinghua Center for Life Sciences , Peking University , Beijing 100871 , China.

Journal of the American Chemical Society
|December 3, 2019
PubMed
まとめ

研究者らは,重要な生物学的活動を持つノートリテルペノイドである前シサナタニンCの最初のエナチオ選択的全合成を達成した. この合成は,新しい金触媒によるサイクロプロパネーションを使用して,重要なビサイクロ[6.1.0]ノンアンのコアを構築した.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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