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Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
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Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

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[FeFe]ヒドロゲネーゼは,COブリッジ付き中間物質のみで動作する,というスペクトロスクープと計算による証拠

James A Birrell1, Vladimir Pelmenschikov2, Nakul Mishra3

  • 1Max Planck Institute for Chemical Energy Conversion , Stiftstrasse 34-36 , 45470 Mülheim an der Ruhr , Germany.

Journal of the American Chemical Society
|December 11, 2019
PubMed
まとめ

[FeFe]ヒドロゲネーゼは,主要中間状態でブリッジングヒドリドではなく,ブリッジングカルボニル (CO) を利用する. この発見は,これらの高度に活性な水素変換酵素のメカニズムを明らかにします.

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