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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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動的に決定されたステレオ選択性における結合記憶

Vladislav A Roytman1, Shengfei Jin2, Vu T Nguyen2

  • 1Department of Chemistry , Texas A&M University , P.O. Box 30012, College Station , Texas 77842 , United States.

Journal of the American Chemical Society
|December 20, 2019
PubMed
まとめ

サイクロヘキセンの炭酸性環収縮は異常な選択性を示し,単一の移行状態から逆転と保持製品の両方を形成する. この選択性は,反応ダイナミクスにおける新しい結合と古い結合の異なる行動から生じる.

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