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Updated: Jan 1, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

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炭酸によって誘導される非活性メチレンのエナンチオセレクティブC-H乳酸化

Marco Cianfanelli1, Giorgio Olivo1, Michela Milan1

  • 1QBIS Research Group, Institut de Química Computacional i Catàlisi (IQCC), and Departament de Química , Universitat de Girona , Campus Montilivi , Girona E-17071 , Catalonia , Spain.

Journal of the American Chemical Society
|December 28, 2019
PubMed
まとめ

この研究は,例外的な選択性を持つキラル・ガンマ・ラクトンを生成するための新しいマンガン触媒化C-H酸化方法を導入しています. この反応は,単純なカルボキシル酸誘導基と過酸化水素を用いて,サイト,エナンチオ,および化学選択性を効率的に制御する.

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