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関連する概念動画

Chair Conformation of Cyclohexane02:02

Chair Conformation of Cyclohexane

17.7K
The chair conformation is the most stable form of cyclohexane due to the absence of angle and torsional strain. The absence of angle strain is a result of cyclohexane’s bond angle being very close to the ideal tetrahedral bond angle of 109.5° in its chair conformer. Similarly, the torsional strain is also absent owing to the perfectly staggered arrangement of bonds.
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this...
17.7K
Conformations of Cyclohexane02:11

Conformations of Cyclohexane

15.0K
Cyclohexane does not exist in a planar form due to the high angle and torsional strain it would experience in the planar structure. Instead, it adopts non-planar chair and boat conformations.
The chair form is the most stable and derives its name from its resemblance to the “easy chair.” In the chair conformation, two carbon atoms are arranged out-of-plane — one above and one below, minimizing the torsional strain. In the chair form, the bond angle is very close to the ideal...
15.0K
Structure of Alkanes02:23

Structure of Alkanes

32.1K
The formation of carbon-carbon bonds leading to the creation of the carbon chain is the basis of organic chemistry. August Kekulé and Archibald Scott Couper independently developed this idea of carbon chain formation.
Hydrocarbons are the simplest organic compounds composed of carbons and hydrogens. Based on the bond order between carbons, the hydrocarbons are further classified into alkanes, alkenes, and alkynes. 
Alkanes are the simplest hydrocarbons with sp3 hybrid carbon atoms....
32.1K
Conformations of Cycloalkanes02:29

Conformations of Cycloalkanes

13.9K
Adolf von Baeyer attempted to explain the instabilities of small and large cycloalkane rings using the concept of angle strain — the strain caused by the deviation of bond angles from the ideal 109.5° tetrahedral value for sp3  hybridized carbons. However, while cyclopropane and cyclobutane are strained, as expected from their highly compressed bond angles, cyclopentane is more strained than predicted, and cyclohexane is virtually strain-free. Hence, Baeyer’s theory that...
13.9K
Conformations of Butane02:20

Conformations of Butane

17.4K
Unlike ethane and propane that have only two major conformations, butane has more than two conformers. The staggered form of butane in which the bulky methyl groups on the two carbons are placed on opposite sides, that is, at a dihedral angle of 180°, is the lowest energy, most stable form — called the anti conformer. This conformation is stabilized due to the absence of steric repulsion between the largely spaced out methyl groups. The other two staggered conformations are...
17.4K
Conformations of Ethane and Propane02:18

Conformations of Ethane and Propane

16.6K
In an organic molecule, free rotation about the carbon-carbon single bond results in energetically different conformers of the molecule. Due to this rotation, called the internal rotation, ethane has two major conformations — staggered and eclipsed.
Staggered conformation is a low energy and more stable conformation with the C-H bonds on the front carbon placed at 60°dihedral angles relative to the C-H bonds on the back carbon, leading to a reduced torsional strain. In staggered...
16.6K

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関連する実験動画

Updated: Dec 31, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

12.0K

断片型コンストラクションの炭化水素ベルト

Qian Zhang1, Yan-E Zhang1, Shuo Tong1

  • 1MOE Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology, Department of Chemistry , Tsinghua University , Beijing , 100084 , China.

Journal of the American Chemical Society
|January 7, 2020
PubMed
まとめ

研究者らはリソルシナレンの原料を使って 新しい炭化水素ベルトを作りました これらの分子帯は 選択的にニトロメタンやp-キセレンのような小さな分子を宿すことができます

科学分野:

  • 超分子化学
  • 有機合成
  • 材料科学

背景:

  • リソルシナレンのマクロサイクルは複雑な分子構造を構築するための多用途のプラットフォームです.
  • 適合した穴を持つ新しい宿主物質の開発は 分子認識と分離に不可欠です

研究 の 目的:

  • リソルシナレンから派生した新種の炭化水素ベルトを合成し,特徴づけること.
  • これらの新しい分子帯の構造的多様性と宿主-ゲストの性質を探求する.

主な方法:

  • トリフレーション,移行金属触媒ビニレーション,および分子内オレフィンメタテシスを含むすべてのフィヨルドを閉じる戦略を使用した.
  • オレフィンとベンゼンのサブユニットを選択的に水素化し,多様な炭化水素構造を生成する.
  • 配合された化合物は,光学および結晶学的技術を用いて特徴づけられた.

主要な成果:

  • 二重鎖のマクロサイクリックベルト構造を持つベルト[n]アレン[n]トロピリデン (n = 4, 6) を成功して合成した.
  • 分子帯の穴は 断片化された体であることが判明しました
  • ニトロメタンやp-キセレンなどの小さな分子を選択的に含める能力を示した.

さらに関連する動画

Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography
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Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography

Published on: October 21, 2018

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Kinematic History of a Salient-recess Junction Explored through a Combined Approach of Field Data and Analog Sandbox Modeling
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Kinematic History of a Salient-recess Junction Explored through a Combined Approach of Field Data and Analog Sandbox Modeling

Published on: August 5, 2016

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関連する実験動画

Last Updated: Dec 31, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

12.0K
Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography
12:18

Pore-scale Imaging and Characterization of Hydrocarbon Reservoir Rock Wettability at Subsurface Conditions Using X-ray Microtomography

Published on: October 21, 2018

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Kinematic History of a Salient-recess Junction Explored through a Combined Approach of Field Data and Analog Sandbox Modeling
06:55

Kinematic History of a Salient-recess Junction Explored through a Combined Approach of Field Data and Analog Sandbox Modeling

Published on: August 5, 2016

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結論:

  • 開発された合成戦略は,新しい炭化水素ベルトへのアクセスを容易にする.
  • これらの分子帯は 独特の構造特性を有し 効果的な合成宿主材料として機能します
  • 小さな分子の選択的含有は,宿主-ゲスト化学と分離科学におけるそれらの潜在的な応用を強調する.