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Updated: Dec 29, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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エナンチオセレクティブ・トータル・シンセシス (+) コリミンと (-) デフォルミルコリミン

Benxiang Zhang1, Xiaoqing Wang1, Chaozhong Li1,2

  • 1Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis , Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road , Shanghai 200032 , P.R. China.

Journal of the American Chemical Society
|January 30, 2020
PubMed
まとめ

この研究は,11段階の戦略を用いたアカミリンアルカロイド (+) - コリミンと (-) - デフォルミルコリミンの最初のエナンチオセレクティブ・トータル合成を示しています. この新しいアプローチは,これらの複雑な天然製品のための重要なステレオセンターとリングシステムを効率的に構築します.

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