液体 有機 フレーム ワーク: 単一 ネットワーク の"水道 工 の 悪夢" 二連鎖 立方体 液体 水晶
Silvio Poppe1, Xiaohong Cheng1,2, Changlong Chen3
1Institute of Chemistry , Martin-Luther-University Halle-Wittenberg , Kurt-Mothes-Straße 2 , 06120 Halle , Germany.
Journal of the American Chemical Society
|February 6, 2020
まとめ
研究者は新しいボラポリフィルを開発し 最もシンプルな柔らかい物質の立方相を作りました この独特の液晶構造は のようなアロマティック棒と 水素結合のグリッドを特徴としています
科学分野:
- 材料科学
- 超分子化学
- 液体結晶
背景:
- 柔らかい物質の相は 複雑な自己組織化を示します
- オーダーされたナノ構造を設計することは 先進的な材料にとって極めて重要です
研究 の 目的:
- 新しいボラポリフィルを合成し特徴づけること.
- 新しい柔らかい物質の立方相の形成を調査する
主な方法:
- 特定の芳香核と機能群を持つボラポリフィルの合成
- 構造分析は,X線 difraksionのような技術を使用して,相の振る舞いを決定します.
主要な成果:
- 立方体液晶相 (Pm3̅m) の最初の"水道工の悪夢のネットワーク"の形成
- 構造は,状のグリッドを形成する芳香棒の束で構成されています.
- サイドチェーンは,この相互に浸透しないフレームワークの残りのボリュームを効果的に満たします.
結論:
- ボラポリフィルは,知られている最も単純な軟質の立方相に自己組み立てることができます.
- この発見は 潜在的応用のための 新しい高度な有機的枠組みを提供します
関連する概念動画
Network Covalent Solids
15.9K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
15.9K
Metallic Solids
20.3K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.3K
Fluid Mosaic Model
15.3K
Scientists identified the plasma membrane in the 1890s and its principal chemical components (lipids and proteins) by 1915. The model for plasma membrane structure, proposed in 1935 by Hugh Davson and James Danielli, was the first model to be widely accepted in the scientific community. The model was based on the plasma membrane's "railroad track" appearance in early electron micrographs. Davson and Danielli theorized that the plasma membrane's structure resembled a sandwich...
15.3K
Molecular and Ionic Solids
19.7K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
19.7K
The Fluid Mosaic Model
175.8K
The fluid mosaic model was first proposed as a visual representation of research observations. The model comprises the composition and dynamics of membranes and serves as a foundation for future membrane-related studies. The model depicts the structure of the plasma membrane with a variety of components, which include phospholipids, proteins, and carbohydrates. These integral molecules are loosely bound, defining the cell’s border and providing fluidity for optimal function.
175.8K
Lattice Centering and Coordination Number
11.2K
The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Types of Unit Cells
Imagine taking a large number of identical...
11.2K


