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Updated: Dec 28, 2025

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

Published on: January 21, 2020

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活性化されていないアニリンを酸化してN-アリルニトロイドを生成する

Tianning Deng1, Wrickban Mazumdar1, Russell L Ford1

  • 1Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061, United States.

Journal of the American Chemical Society
|February 12, 2020
PubMed
まとめ

新しい方法は,2代入のアニリンを低温で酸化して,N-アリルニトロイド中間物質を生成する. これは,スパイロサイクルの3Hインドルとベンザゼピノンを含む機能化されたN-ヘテロサイクルの合成を可能にします.

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