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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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CO2削減のための有機単層の金属触媒の分子結合強度の制御

Jing Zhang1, Shyam Deo2, Michael J Janik2

  • 1Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States.

Journal of the American Chemical Society
|February 22, 2020
PubMed
まとめ

研究者は,二酸化炭素の削減のための触媒の活性と選択性を制御する新しい方法を開発しました. 有機モノレイヤーで触媒表面を改造することで,一酸化炭素の生産効率を高め,触媒の無効化を軽減しました.

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Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Reduction of Alkenes: Catalytic Hydrogenation

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Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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