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Updated: Dec 27, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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ロジウム触媒によるアリルC-Hアミネーションのメカニズム

Robert J Harris1, Jiyong Park2,3, Taylor A F Nelson1

  • 1Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.

Journal of the American Chemical Society
|March 3, 2020
PubMed
まとめ

この研究は,Cp*Rh複合体を用いて,触媒性アリルC-Hアミネーションのメカニズムを明らかにしている. 酸C-H活性化と,Rh (IV) 中間物質を通じた酸化誘導による還元性排出が示され,触媒サイクルが完了する.

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