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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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支持された単一原子触媒による異質な水素形成の見通し

Jonas Amsler1, Bidyut B Sarma2, Giovanni Agostini3

  • 1Institute of Catalysis Research and Technology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany.

Journal of the American Chemical Society
|March 7, 2020
PubMed
まとめ

オキシドのロジウム単原子触媒は,様々な水酸化活性を示している. CeO2は高い活性を維持し,MgOは閉じ込め効果のために低い反応性を示し,安定性と活性性のバランスを強調します.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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