グラフェンのガス浸透性の限界
P Z Sun1,2, Q Yang1,2, W J Kuang1
1Department of Physics and Astronomy, University of Manchester, Manchester, UK.
Nature
|March 13, 2020
まとめ
欠陥のないグラフェンはほとんどのガスに浸透しないため,新しい実験により検出限界が高くなります. しかし水素は2段階の原子プロセスを経て 独特にグラフェンに浸透します
科学分野:
- 材料科学
- ナノテクノロジー
- 物理化学
背景:
- 炭素原子の単一層であるグラフェンは 理論的にも実験的にも ガスに浸透しないと考えられています
- これまでの実験では,毎秒10^5から10^6原子未満のガス浸透を検出することができなかった.
研究 の 目的:
- 欠陥のないグラフェンの不透性のより正確な限界を確立する.
- グラフェンを通した 異常な水素の浸透を 調べるために
主な方法:
- 欠陥のないグラフェンで密封された小さな単結晶容器を使用します.
- ガス浸透度を測定するために非常に敏感な検出方法を使用します.
主要な成果:
- 以前の研究より8~9度高い精度で グラフェンの不透性を確立した.
- ヘリウム,ネオン,窒素,酸素,アルゴン,クリプトン,クセノンの浸透は観察されなかった.
- 大量の水素の浸透を検出した 分子の大きさに基づく予想とは対照的に
結論:
- 欠陥のないグラフェンは,ほとんどのガスに対して極度の不透性を示します.
- 水素の浸透は,波紋と原子の反転で解離を含む2段階のプロセスを経て発生します.
- この発見は2次元材料の特性や用途を理解するために極めて重要です.
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