メタル-メタル協同酸化添加による二核ニッケル複合体におけるH2対内分子C-H活性化

Hendrik Stevens1, Peng-Cheng Duan1, Sebastian Dechert1

  • 1Universität Göttingen, Institut für Anorganische Chemie, Tammannstrasse 4, D-37077 Göttingen, Germany.

まとめ

この研究は,強力なダイニッケル (I) 還元剤を可逆的に生成できる新しいニッケル複合体を導入しています. このディニケール (I) 中間物質は,不安定な種を隔離せずに2電子基板の減少を可能にし,挑戦的な化学変換のための新しいプラットフォームを提供します.

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