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Updated: Dec 26, 2025

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
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Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes

Published on: September 12, 2018

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アクセスキラルα-アリルカルボニル化合物への非対称的なヨドニウム-[3,3]-シグマトロピク再配置

Junsong Tian1, Fan Luo1, Qifeng Zhang1

  • 1Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China.

Journal of the American Chemical Society
|March 14, 2020
PubMed
まとめ

この研究は,アリルイオダンを用いた新しい非対称 [3,3]-シグマトロピク再配置を導入している. この方法は,キラル-2-オクサゾリンのエナチオセレクティブα-アリレーションを達成し,貴重なキラルα-アリルカルボニル化合物を生成します.

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