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Updated: Dec 22, 2025

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
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Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst

Published on: April 22, 2016

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可視光誘導のラジカルカーボサイクリング/ジェム - 金触媒とアリルイオデスの間のトリプルエネルギー転送による二酸化反応

Lumin Zhang1, Xiaojia Si1, Frank Rominger1

  • 1Organisch-Chemisches Institut, Heidelberg University, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.

Journal of the American Chemical Society
|May 1, 2020
PubMed
まとめ

新しい方法により,これまで知られていなかったベンゾフラン,インドル,ベンゾチオフェンベースのベンジル基石二ボロナートを合成することができる. 生物学的関連性のある化合物や 医薬品の製造に不可欠なものです

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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization12:19

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Cycloaddition Reactions: MO Requirements for Photochemical Activation

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
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