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Updated: Dec 22, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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活性化されていないアルキルブロミドを含む3つの構成要素,中断されたラジカルヘック/アリル置換カスケード

Huan-Ming Huang1, Peter Bellotti1, Philipp M Pflüger1

  • 1Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149 Münster, Germany.

Journal of the American Chemical Society
|May 8, 2020
PubMed
まとめ

この研究は,活性化されていないアルキルブロミドを用いたダイエンの効率的な1,4機能化のための新しいパラジアム触媒基結合を導入する. この方法は,複数のステレオ中心を持つ複雑な分子を合成する際の制限を克服します.

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