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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

Published on: February 16, 2020

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リバーシブルカタリシスにおける選択性の問題を克服する:高い運動制御を示す転送水素化

Benjamin N Bhawal1,2, Julia C Reisenbauer1,2, Christian Ehinger1

  • 1ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|June 2, 2020
PubMed
まとめ

この研究は,枝分かれしたニトリルの選択的合成のための新しい可逆転移ヒドロシアン化法を導入する. この突破は複雑な化学合成に HCN のない実用的なアプローチを提供します

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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