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Updated: Dec 19, 2025

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

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イリジウム触媒による酸化補助によるオキシムからヒドロキシラミンへの非対称水素化

Josep Mas-Roselló1, Tomas Smejkal2, Nicolai Cramer3

  • 1Ecole Polytechnique Fédérale de Lausanne (EPFL), School of Basic Sciences, Institute of Chemical Sciences and Engineering, Laboratory of Asymmetric Catalysis and Synthesis, BCH 4305, CH-1015 Lausanne, Switzerland.

Science (New York, N.Y.)
|June 6, 2020
PubMed
まとめ

この研究は,キラルヒドロキシラミン誘導体を生成するオキシメスの非対称な水素化のための効率的なイリジウム (III) 触媒を導入する. この方法は,価値あるN-アルコキシアミンの新しい経路を提供して,N-O結合の割れ目を回避します.

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