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Updated: Dec 18, 2025

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中性エオシンYが直接水素原子移転光触媒として促進した急激な微笑の再配置

Jianming Yan1, Han Wen Cheo1, Wei Kiat Teo1

  • 1Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.

Journal of the American Chemical Society
|June 17, 2020
PubMed
まとめ

研究者は可視光と光触媒を用いた新しいN-ヘテロサイクルの合成方法を開発した. この効率的なプロセスは 抗がん活性を持つ化合物を生成し 合成化学の 重要な進歩を示しています

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Photochemical Electrocyclic Reactions: Stereochemistry

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The presence of electron-donating, electron-withdrawing, or conjugating groups adjacent to a radical center, imparts electronic stabilization to the radicals. Examples of such electronically-stabilized radicals are triphenylmethyl, tetramethylpiperidine‐N‐oxide, and 2,2‐diphenyl‐1‐picrylhydrazyl. These radicals are remarkably stable and are known as persistent radicals. Some of the persistent radicals can even be isolated and purified.
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