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Updated: Dec 18, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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二金属ロジウム-インジウム複合体を用いたアリルC-F結合の触媒水解

James T Moore1, Connie C Lu1

  • 1Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States.

Journal of the American Chemical Society
|June 20, 2020
PubMed
まとめ

新しいロジウム・インジウム触媒は,水素と塩基を用いてアリル化合物からフッ素を効率的に除去します. この突破により 温和な条件下で 難易度の高いC−F結合の 化が可能になりました

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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