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Updated: Dec 17, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Published on: May 26, 2019

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アルキリデン・サイクロプロパンのC-C σ結合の活性化と機能化

Richard Y Kong1, Mark R Crimmin1

  • 1Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, White City, London W12 0BZ, U.K.

Journal of the American Chemical Society
|June 27, 2020
PubMed
まとめ

アルミニウム (I) とマグネシウム (I) の化合物は,協調した酸化添加ではなく,段階的なメカニズムを通じて,緊張されたサイクロプロパンC-C結合を活性化します. この洞察は,C−C結合活性化のための新しいマグネシウム触媒化水酸化反応を可能にします.

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