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Updated: Dec 17, 2025

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

Published on: January 21, 2020

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インドールのニオケタライズド・トレイスレス・ディレクテッド・C3・セレクティブ・C・Hボリレーション

Ya-Ming Tian1, Xiao-Ning Guo1, Zhu Wu1

  • 1Institut für Anorganische Chemie, and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

Journal of the American Chemical Society
|June 30, 2020
PubMed
まとめ

新しいニッケル触媒法により,C3位置でのインドルの痕跡のない,指向されたC-Hボリレーションが可能である. この効率的なプロトコルは,その後のスズキ-ミヤウラクロスカップリングを可能にし,機能化されたヘテロアレンを作成します.

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