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Updated: Dec 15, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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合理的リガンド設計による銀触媒プロパルギルC-H結合アミネーション

Minsoo Ju1, Emily E Zerull1, Jessica M Roberts1

  • 1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States.

Journal of the American Chemical Society
|July 14, 2020
PubMed
まとめ

研究者は,非対称なC-Hアミネーションのための新しい銀触媒法を開発し,エナチオ濃縮されたγ-アミノアルコールを生成した. この効率的なプロセスは新しいリガンドを使用し,高い選択性を持つ多用途な製品を提供します.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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