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Updated: Dec 15, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
12:19

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

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活性ルテニウムフィッシャーカルベンのエネとサイクリックエノールエーテルの交替カスケードメタテシスポリメリゼーション

Xuelin Sui1, Tianqi Zhang1, Alec B Pabarue1

  • 1School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive NW, Atlanta, Georgia 30332, United States.

Journal of the American Chemical Society
|July 15, 2020
PubMed
まとめ

ルテニウムアルコキシメチリデン複合体は,しばしば惰性であり,現在,交互のリング開きメタテシスポリメリゼーションを駆動することができる. この突破は,フィッシャー型カーベンの触媒を用いて,制御された性質を持つ分解性ポリマーの作成を可能にします.

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