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Updated: Dec 14, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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ヘキサフェニルベンゼンから1,2,3,4,5,6-ヘキササイクロヘキサン

Marcel Dillenburger1, Zijie Qiu1, Cheng-Wei Ju1,2

  • 1Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.

Journal of the American Chemical Society
|July 16, 2020
PubMed
まとめ

研究者はヘキサフェニルベンゼンを水素化し,部分的に水素化されたヘキササイクロヘキシルベンゼン (HCB) と完全に水素化された1,2,3,4,5,6-ヘキササイクロヘキサン (HCC) 分子を生成した. 構造分析により,サイクロヘキシル置換剤の独特の形状と配置が明らかになった.

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