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Updated: Dec 14, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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塩で良い:中性pHでの水性環開きメタテシスポリメリゼーション

Jeffrey C Foster1, Marcus C Grocott1, Lucy A Arkinstall1

  • 1School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, United Kingdom.

Journal of the American Chemical Society
|July 17, 2020
PubMed
まとめ

水性環開きメタテシスポリメリゼーション (ROMP) は,ルテニウム触媒を無効化するクロライドイオンに敏感です. 塩化塩を加えると,モノメアの変換と制御が促進され,水中の二ブロック共ポリマー合成が可能になる.

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