Pd/Ni→Si-F→ルイス酸相互作用によるフローロシラン活性化:触媒性シラ・ネギシ結合への入り口

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Updated: Dec 13, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

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Hajime Kameo1, Hiroki Yamamoto1, Koki Ikeda1

  • 1Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.

Journal of the American Chemical Society
|July 26, 2020
PubMed
まとめ

この研究では,移行金属とルイス酸を用いたフッ素シランの活性化のための新しい方法が明らかにされ,最初の触媒性シリコン-フッ素結合の活性化が可能になりました. この突破は,高度な化学合成のための新しいシラ・ネギシ結合を促進します.

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